M.A.Sc Research

Ph.D Research

Publications




Engineering Infra-Red Photon Absorbing Materials for Organic Solar Cells:

M.A.Sc. (2007-2009)- University of Toronto - Department of Chemical Engineering and Applied Science - Supervisor Prof. Timothy Bender

The goal of this thesis was to develop a material to absorb infra-red light, with the requirement that it is capable of being incorporated into an organic solar cell. Although they tend to have lower efficiencies, organic solar cells can be made less expensively, are flexible, and therefore can be used in novel applications! If this really tickles your curioustiy then visit Prof. Bender's Website




The Utilization of Bark to Make Rigid Polyurethane Foams

(Started Fall - 2010)- University of Toronto - Faculty of Forestry - Supervisor Prof. Ning Yan

My research focused on the extraction of biomass from the bark of trees, and utilizing this to make rigid polyurethane foams (PUF).



PUFs are used for various applications including insulation in appliances, residential housing, and in the interior mouldings of cars.



Polyols, one of the reactants to make a polyurethane, are traditionally from synthetic petrochemicals, however natural biopolymers can be used as substitutes, while also imparting unique mechanical properties.



From the next diagram it becomes clear that bark is a complex material, with a great diversity in molecular structures, and most importantly featuring many hydroxyl containing compounds. These compounds can be high or low molecular weight, varying functionality (number of hydroxyl groups per molecule), and contain different hydroxyl groups (primary, secondary, phenolic).



It is this great variation in molecular structure that obscures the relationship between the natural biopolymers and the resultant foam properties, which will hopefully be uncovered by my research.

Link: Professor Ning Yan's lab website

Publications

1. D’Souza, J.; Yan, N. Producing Bark-based Polyols through Liquefaction: Effect of Liquefaction Temperature. ACS Sustain. Chem. Eng. 2013, 1, 534–540.

This work was featured on the cover of the ACS Journal Sustainable Chemistry and Engineering





2. D’Souza, J.; Camargo, R.; Yan, N. Polyurethane foams made from liquefied bark-based polyols. J. Appl. Polym. Sci. 2014, 131, 40599.





3. D’Souza, J.; George, B.; Camargo, R.; Yan, N. Synthesis and characterization of bio-polyols through the oxypropylation of bark and alkaline extracts of bark. Ind. Crops Prod. 2015, 76, 1-11.





4. D’Souza, J.; Wong, S.; Camargo, R.; Yan, N. Solvolytic Liquefaction of Bark: Understanding the Role of Polyhydric Alcohols and Organic Solvents on Polyol Characteristics. ACS Sustain. Chem. Eng. 2016, 4(3), 851-861.





5. D’Souza, J.; Camargo, R.; Yan, N. Biomass liquefaction and alkoxylation: A review of structural characterization methods for bio-based polyols. Poly. Rev. 2017, 1-27.